Evaluation of asphaltene adsorption on minerals of dolomite and sandstone formations in two and three-phase systems
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Abstract
Asphaltene adsorption on reservoir rock minerals causes wettability alteration and pore plugging which subsequently reduces crude oil production. Also, it has a negative effect on the efficiency of production and enhanced oil recovery operations. In this study, the adsorption of extracted asphaltenes of two samples of Iranian oil fields on dolomite, quartz, and magnetite was investigated in two-and three-phase systems in both static and dynamic flow modes. Mineral adsorbents were analyzed by Brunauer–Emmett–Teller and X-ray fluorescence methods. Also, several laboratory tests including elemental analysis, field emission scanning electron microscopy, and Fourier transform infrared spectroscopy were carried out to characterize asphaltenes. The results showed that in addition to the effect of known parameters such as asphaltenes concentration and specific surface area of the solid phase, the water phase also affects the amount of asphaltenes adsorption. The adsorption amount of asphaltenes increases with increasing the specific surface area of adsorbent (decreasing particle size) and increasing the initial concentration of asphaltenes, and decreases with the addition of water to the two-phase system. The static adsorption amount of asphaltenes in a two-phase system can be up to 90% higher than the adsorption amount in a three-phase system. Doubling the fluid flow rate in dynamic adsorption significantly (by about 20%) reduces the asphaltenes adsorption, which could be a sign of physical adsorption of asphaltenes on adsorbents. The structure and elemental composition of asphaltenes also have a significant effect on asphaltenes adsorption. The asphaltene sample, which had a more aromatic nature and high nitrogen content, had higher adsorption on reservoir rock minerals. Finally, fitting the adsorption equilibrium models with experimental data reveals that the adsorption isotherm model depends on the type and particle size of the adsorbents and the concentration and type of asphaltenes.
Cited as: Mohammadi, M.R., Bahmaninia, H., Ansari, S., Hemmati-Sarapardeh, A., Norouzi-Apourvari, S., Schaffie, M., Ranjbar, M. Evaluation of asphaltene adsorption on minerals of dolomite and sandstone formations in two and three-phase systems. Advances in Geo-Energy Research, 2021, 5(1), 39-52, doi: 10.46690/ager.2021.01.05
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Acevedo, S., Ranaudo, M.A., Garcı́a, C., et al. Importance of asphaltene aggregation in solution in determining the adsorption of this sample on mineral surfaces. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2000, 166(1-3): 145-152.
Adams, J.J. Asphaltene adsorption, a literature review. Energy & Fuels, 2014, 28(5): 2831-2856.
Ahooei, A., Norouzi-Apourvari, S., Hemmati-Sarapardeh, A., et al. Experimental study and modeling of asphaltene deposition on metal surfaces via electrodeposition process: The role of ultrasonic radiation, asphaltene concentration and structure. Journal of Petroleum Science and Engineering, 2020, 195: 107734.
Akbarzadeh, K., Hammami, A., Kharrat, A., et al. Asphaltenes—problematic but rich in potential. Oilfield Review, 2007, 19(2): 22-43.
Alboudwarej, H., Pole, D., Svrcek, W.Y., et al. Adsorption of asphaltenes on metals. Industrial & Engineering Chemistry Research, 2005, 44(15): 5585-5592.
Asemani, M., Rabbani, A.R. Oil-oil correlation by ftir spectroscopy of asphaltene samples. Geosciences Journal, 2016, 20(2): 273-283.
Calemma, V., Iwanski, P., Nali, M., et al. Structural characterization of asphaltenes of different origins. Energy & Fuels, 1995, 9(2): 225-230.
Carbognani, L. Effects of iron compounds on the retention of oil polar hydrocarbons over solid sorbents. Petroleum Science and Technology, 2000, 18(3-4): 335-360.
Clementz, D.M. Alteration of rock properties by adsorption of petroleum heavy ends: Implications for enhanced oil recovery. Paper SPE 10683 Presented at SPE Enhanced Oil Recovery Symposium, Tulsa, Oklahoma, 4-7 April, 1982.
Collins, S.H., Melrose, J.C. Adsorption of asphaltenes and water on reservoir rock minerals. Paper SPE 11800 Presented at SPE Oilfield and Geothermal Chemistry Symposium, Denver, Colorado, 1-3 June, 1983.
Dehaghani, A.H.S., Daneshfar, R. How much would silica nanoparticles enhance the performance of low-salinity water flooding? Petroleum Science, 2019, 16(3): 591-605.
Dubey, S.T., Waxman, M.H. Asphaltene adsorption and desorption from mineral surfaces. SPE Reservoir Engineering, 1991, 6(3): 389-395.
Dudášová, D., Flåten, G.R., Sjöblom, J., et al. Study of asphaltenes adsorption onto different minerals and clays: Part 2. Particle characterization and suspension stability. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2009, 335(1-3): 62-72.
Dudášová, D., Simon, S., Hemmingsen, P.V., et al. Study of asphaltenes adsorption onto different minerals and clays: Part 1. Experimental adsorption with uv depletion detection. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2008, 317(1-3): 1-9.
Ezeonyeka, N.L., Hemmati-Sarapardeh, A., Husein, M.M. Asphaltenes adsorption onto metal oxide nanoparticles: A critical evaluation of measurement techniques. Energy & Fuels, 2018, 32(2): 2213-2223.
Fakher, S., Ahdaya, M., Elturki, M., et al. Critical review of asphaltene properties and factors impacting its stability in crude oil. Journal of Petroleum Exploration and Production Technology, 2020, 10: 1183-1200.
Foo, K.Y., Hameed, B.H. Insights into the modeling of adsorption isotherm systems. Chemical Engineering Journal, 2010, 156(1): 2-10.
Franco, C.A., Montoya, T., Nassar, N.N., et al. Adsorption and subsequent oxidation of colombian asphaltenes onto nickel and/or palladium oxide supported on fumed silica nanoparticles. Energy & Fuels, 2013, 27(12): 7336-7347.
Friberg, S.E., Yang, H., Midttun, Ø., et al. Location of crude oil resin molecules at an interface—model system. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1998, 136(1-2): 43-49.
Garrouch, A.A., Al-Ruhaimani, F.A. Simple models for permeability impairment in reservoir rocks caused by asphaltene deposition. Petroleum Science and Technology, 2005, 23(7-8): 811-826.
Gharbi, K., Benyounes, K., Khodja, M. Removal and prevention of asphaltene deposition during oil production: A literature review. Journal of Petroleum Science and Engineering, 2017, 158: 351-360.
González, G., Middea, A. The properties of the calcite—solution interface in the presence of adsorbed resins or asphaltenes. Colloids and Surfaces, 1988, 33: 217-229.
González, G., Moreira, M.B.C. Chapter 9 the adsorption of asphaltenes and resins on various minerals. Developments in Petroleum Science, 1994, 40: 207-231.
Gonzalez, V., Taylor, S.E. Asphaltene adsorption on quartz sand in the presence of pre-adsorbed water. Journal of Colloid and Interface Science, 2016, 480: 137-145.
Gou, Q., Xu, S. Quantitative evaluation of free gas and adsorbed gas content of Wufeng-Longmaxi shales in the Jiaoshiba area, Sichuan Basin, China. Advances in Geo-Energy Research, 2019, 3(3): 258-267.
Hassanpouryouzband, A., Joonaki, E., Taghikhani, V., et al. New two-dimensional particle-scale model to simulate asphaltene deposition in wellbores and pipelines. Energy & Fuels, 2017, 32(3): 2661-2672.
Hemmati-Sarapardeh, A., Ameli, F., Ahmadi, M., et al. Effect of asphaltene structure on its aggregation behavior in toluene-normal alkane mixtures. Journal of Molecular Structure, 2020, 1220: 128605.
Hemmati-Sarapardeh, A., Dabir, B., Ahmadi, M., et al. Toward mechanistic understanding of asphaltene aggregation behavior in toluene: The roles of asphaltene structure, aging time, temperature, and ultrasonic radiation. Journal of Molecular Liquids, 2018, 264: 410-424.
Hu, X., Yutkin, M.P., Hassan, S., et al. Asphaltene adsorption from toluene onto silica through thin water layers. Langmuir, 2018, 35(2): 428-434.
Inam, E., Etim, U.J., Akpabio, E.G., et al. Process optimization for the application of carbon from plantain peels in dye abstraction. Journal of Taibah University for Science, 2017, 11(1): 173-185.
Joonaki, E., Burgass, R., Hassanpouryouzband, A., et al. Comparison of experimental techniques for evaluation of chemistries against asphaltene aggregation and deposition: New application of high-pressure and high-temperature quartz crystal microbalance. Energy & Fuels, 2017, 32(3): 2712-2721.
Joonaki, E., Hassanpouryouzband, A., Burgass, R., et al. Effects of waxes and the related chemicals on asphaltene aggregation and deposition phenomena: Experimental and modeling studies. ACS Omega, 2020, 5(13): 7124-7134.
Joshi, N.B., Mullins, O.C., Jamaluddin, A., et al. Asphaltene precipitation from live crude oil. Energy & Fuels, 2001, 15(4): 979-986.
Kecili, R., Hussain, C.M. Mechanism of adsorption on nanomaterials. Nanomaterials in Chromatography, 2018, 2018: 89-115.
Khormali, A., Sharifov, A.R., Torba, D.I. Experimental and modeling study of asphaltene adsorption onto the reservoir rocks. Petroleum Science and Technology, 2018, 36(18): 1482-1489.
Kokal, S., Tang, T., Schramm, L., et al. Electrokinetic and adsorption properties of asphaltenes. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1995, 94(2-3): 253-265.
Lamontagne, J., Dumas, P., Mouillet, V., et al. Comparison by fourier transform infrared (ftir) spectroscopy of different ageing techniques: Application to road bitumens. Fuel, 2001, 80(4): 483-488.
Langmuir, I. The constitution and fundamental properties of solids and liquids. Part i. Solids. Journal of the American Chemical Society, 1916, 38(11): 2221-2295.
Leon, O., Rogel, E., Espidel, J., et al. Asphaltenes: Structural characterization, self-association, and stability behavior. Energy & Fuels, 2000, 14(1): 6-10.
Li, A., Han, W., Fang, Q., et al. Experimental investigation of methane adsorption and desorption in water-bearing shale. Capillarity, 2020, 3(3): 45-55.
Lopez-Linares, F., Carbognani, L., Hassan, A., et al. Adsorption of athabasca vacuum residues and their visbroken products over macroporous solids: Influence of their molecular characteristics. Energy & Fuels, 2011, 25(9): 4049-4054.
Marczewski, A.W., Szymula, M. Adsorption of asphaltenes from toluene on mineral surface. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2002, 208(1-3): 259-266.
Mazloom, M.S., Hemmati-Sarapardeh, A., Husein, M.M., et al. Application of nanoparticles for asphaltenes adsorption and oxidation: A critical review of challenges and recent progress. Fuel, 2020, 279: 117763.
Mazloom, M.S., Rezaei, F., Hemmati-Sarapardeh, A., et al. Artificial intelligence based methods for asphaltenes adsorption by nanocomposites: Application of group method of data handling, least squares support vector machine, and artificial neural networks. Nanomaterials, 2020, 10(5): 890.
McLean, J.D., Kilpatrick, P.K. Comparison of precipitation and extrography in the fractionation of crude oil residua. Energy & Fuels, 1997, 11(3): 570-585.
Mohammadi, M., Khamehchi, E., Sedighi, M. The prediction of asphaltene adsorption isotherm constants on mineral surfaces. Petroleum Science and Technology, 2014, 32(7): 870-877.
Monjezi, R., Ghotbi, C., Behbahani, T.J., et al. Experimental investigation of dynamic asphaltene adsorption on calcite packs: The impact of single and mixed-salt brine films. The Canadian Journal of Chemical Engineering, 2019, 97(7): 2028-2038.
Mousavi-Dehghani, S.A., Riazi, M.R., Vafaie-Sefti, M., et al. An analysis of methods for determination of onsets of asphaltene phase separations. Journal of Petroleum Science and Engineering, 2004, 42(2-4): 145-156.
Nalwaya, V., Tantayakom, V., Piumsomboon, P., et al. Studies on asphaltenes through analysis of polar fractions. Industrial & Engineering Chemistry Research, 1999, 38(3): 964-972.
Nassar, N.N., Al-Jabari, M.E., Husein, M.M. Removal of asphaltenes from heavy oil by nickel nano and micro particle adsorbents. Presented at Proceedings of the IASTED International Conference, Crete, Greece, 29 September-1 October, 2008.
Nassar, N.N., Hassan, A., Carbognani, L., et al. Iron oxide nanoparticles for rapid adsorption and enhanced catalytic oxidation of thermally cracked asphaltenes. Fuel, 2012, 95: 257-262.
Nassar, N.N., Montoya, T., Franco, C.A., et al. A new model for describing the adsorption of asphaltenes on porous media at a high pressure and temperature under flow conditions. Energy & Fuels, 2015, 29(7): 4210-4221.
Parker, G. Encyclopedia of materials: Science and technology. 2001.
Pernyeszi, T., Patzkó, Á., Berkesi, O., et al. Asphaltene adsorption on clays and crude oil reservoir rocks. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1998, 137(1-3): 373-384.
Petrova, T.M., Fachikov, L., Hristov, J. The magnetite as adsorbent for some hazardous species from aqueous solutions: A review. International Review of Chemical Engineering, 2011, 3(2): 134-152.
Piro, G., Canonico, L.B., Galbariggi, G., et al. Asphaltene adsorption onto formation rock: An approach to asphaltene formation damage prevention. SPE Production & Facilities, 1996, 11(3): 156-160.
Pokrovsky, O., Schott, J., Mielczarski, J. Surface speciation of dolomite and calcite in aqueous solutions. Encyclopedia of Surface and Colloid Science, 2002, 4: 5081-5095.
Priyanto, S., Mansoori, G.A., Suwono, A. Structure and properties of micelles and micelle coacervates of asphaltene macromolecule. Nanotechnology Proceed. Prepar for Presented at 2001 American Institute of Chemical Engineers Annual Meet, 2001.
Sim, S.S., Okatsu, K., Takabayashi, K., et al. Asphaltene-induced formation damage: Effect of asphaltene particle size and core permeability. Paper SPE 95515 Presented at SPE Annual Technical Conference and Exhibition, Dallas, Texas, 9-12 October, 2005.
Syunyaev, R.Z., Balabin, R.M., Akhatov, I.S., et al. Adsorption of petroleum asphaltenes onto reservoir rock sands studied by near-infrared (nir) spectroscopy. Energy & Fuels, 2009, 23(3): 1230-1236.
Taheri-Shakib, J., Hosseini, S.A., Kazemzadeh, E., et al. Experimental and mathematical model evaluation of asphaltene fractionation based on adsorption in porous media: Dolomite reservoir rock. Fuel, 2019, 245: 570-585.
Taheri-Shakib, J., Rajabi-Kochi, M., Kazemzadeh, E., et al. A comprehensive study of asphaltene fractionation based on adsorption onto calcite, dolomite and sandstone. Journal of Petroleum Science and Engineering, 2018, 171: 863-878.
Trejo, F., Ancheyta, J., Rana, M.S. Structural characterization of asphaltenes obtained from hydroprocessed crude oils by sem and tem. Energy & Fuels, 2009, 23(1): 429-439.
Tsiamis, A., Taylor, S.E. Adsorption behavior of asphaltenes and resins on kaolinite. Energy & Fuels, 2017, 31(10): 10576-10587.
Veisi, S., Sefti, M.V., Mahdi, S.M., et al. Adsorption behavior of petroleum asphaltenes dissolved in toluene by low-cost mineral adsorbents. Journal of Oil, Gas and Petrochemical Technology, 2018, 5(1): 1-24.
Wang, J., Buckley, J., PRRC, N.M.T. Standard procedure for separating asphaltenes from crude oils. Petroleum Recovery Research Center 2002.
Wang, M., Hao, Y., Islam, M.R., et al. Aggregation thermodynamics for asphaltene precipitation. AIChE Journal, 2016, 62(4): 1254-1264.
Yarranton, H.W., Fox, W.A., Svrcek, W.Y. Effect of resins on asphaltene self-association and solubility. The Canadian Journal of Chemical Engineering, 2007, 85(5): 635-642.
Zdravkov, B., Čermák, J., Šefara, M., et al. Pore classification in the characterization of porous materials: A perspective. Open Chemistry, 2007, 5(2): 385-395.
Zhao, B., Shaw, J.M. Composition and size distribution of coherent nanostructures in athabasca bitumen and maya crude oil. Energy & Fuels, 2007, 21(5): 2795-2804.
DOI: https://doi.org/10.46690/ager.2021.01.05
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