Using mesoporous thin films as nano-micro-fluidic tools
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Abstract
Achieving active control on small amounts of liquids represents a substantial challenge in both scientific and engineering aspects. Imbibition of fluids in bodies with nanoscale dimensions enables the spontaneous propelling of nano-flows because of the powerful capillarity at small-length scales. Peculiarities of nanopore imbibition at the thin film level lead to distinctive capillary transport phenomena of fluids across the nanopore matrix. This particular imbibition also impacts on the behavior of the in-contact liquid micro-volumes. These both features add versatile alternatives to the high interest in the management of femtolitre to microlitres amounts of liquids. Herein, we show a brief discussion-outlook based on recent advances in the design of versatile tools to attain programmable nano/microfluidics using mesoporous thin film platforms.
Cited as: Berli, C. L. A., Bellino, M. G. Using mesoporous thin films as nano-micro-fluidic tools. Capillarity, 2022, 5(6): 123-127. https://doi.org/10.46690/capi.2022.06.03
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Berli, C. L., Mercuri, M., Bellino, M. G. Modeling the abnormally slow infiltration rate in mesoporous films. Physical Chemistry Chemical Physics, 2017, 19(3): 1731-1734.
Cai, J., Jin, T., Kou, J., et al. Lucas-Washburn equation-based modeling of capillary-driven flow in porous systems. Langmuir, 2021, 37(5): 1623-1636.
Ceratti, D. R., Faustini, M., Sinturel, C., et al. Critical effect of pore characteristics on capillary infiltration in mesoporous films. Nanoscale, 2015, 7(12): 5371-5382.
Gazoni, R. M., Bellino. M. G., Fuertes, M. C., et al. Designed nanoparticle-mesoporous multilayer nanocomposites as tunable plasmonic-photonic architectures for electromagnetic field enhancement. Journal of Materials Chemistry C, 2017, 5(14): 3445-3455.
Gimenez, R., Mercuri, M., Bellino, M. G., el al. Building nanopore-supported 2D vesicles in surfaces. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2019, 573: 1-5.
Gimenez, R., Mercuri, M., Berli, C. L. A., et al. Electrical current nanogeneration driven by spontaneous nanofluidic oscillations. Nanoscale, 2018, 10(7): 3144-3147.
Gimenez, R., Soler-Illia, G. J., Berli, C. L. A., et al. Nanoporeenhanced drop evaporation: When cooler or more saline water droplets evaporate faster. ACS Nano, 2020, 14(3): 2702-2708.
Hidalgo, N., Calvo, M. E., Bellino, M. G., et al. Porous supramolecularly templated optical resonators built in 1D photonic crystals. Advanced Functional Materials, 2011, 21(13): 2534-2540.
Innocenzi, P. Mesoporous ordered films via self-assembly: Trends and perspectives. Chemical Science, 2022, DOI: 10.1039/D2SC04828K. (online)
Innocenzi, P., Malfatti, L. Mesoporous thin films: Properties and applications. Chemical Society Reviews, 2013, 42(9): 4198-4216.
Khalil, A., Rostami, P., Auernhammer, G. K., et al. Mesoporous coatings with simultaneous light-triggered transition of water imbibition and droplet coalescence. Advanced Materials Interfaces, 2021, 8: 2100252.
Khalil, A., Schäfer, F., Postulka, N., et al. Wettability-defined droplet imbibition in ceramic mesopores. Nanoscale, 2020, 12(47): 24228-24236.
Mercuri, M., Berli, C. L., Bellino, M. G. Mesoporous thin films for fluid manipulation. Advanced Materials Interfaces, 2017a, 4(24): 1700970.
Mercuri, M., Gimenez, R., Berli, C. L. A., et al. Configurable 2D nano-flows in mesoporous films using paper patches. RSC Advances, 2018, 8(12): 6414-6418.
Mercuri, M., Pierpauli, K., Bellino, M. G., et al. Complex filling dynamics in mesoporous thin films. Langmuir, 2017b, 33(1): 152-157.
Mercuri, M., Pierpauli, K., Berli, C. L., et al. An open pit nanofluidic tool: Localized chemistry assisted by mesoporous thin film infiltration. ACS Applied Materials & Interfaces, 2017c, 9(19): 16679-16684.
Pizarro, A. D., Berli, C. L., Soler-Illia, G. J., et al. Droplets in underlying chemical communication recreate cell interaction behaviors. Nature Communications, 2022, 13(1): 3047.
Sanchez, C., Boissière, C., Grosso, D., et al. Synthesis and properties of inorganic and hybrid thin films having periodically organized nanoporosity. Chemistry of Materials, 2008, 20(3): 682-737.
Shen, A., Liu, Y., Ali, S. F. A model of spontaneous flow driven by capillary pressure in nanoporous media. Capillarity, 2020, 3(1): 1-7.
Urteaga, R., Mercuri, M., Gimenez, R., et al. Spontaneous water adsorption-desorption oscillations in mesoporous thin films. Journal of Colloid and Interface Science, 2019, 537: 407-413.
Vincent, O., Marguet, B., Stroock, A. D. Imbibition triggered by capillary condensation in nanopores. Langmuir, 2017, 33(7): 1655-1661.
Xue, Y., Markmann, J., Duan, H., et al. Switchable imbibition in nanoporous gold. Nature Communications, 2014, 5(1): 4237.
Zeng, F., Zhang, Q., Guo, J., et al. Capillary imbibition of confined water in nanopores. Capillarity, 2020, 3(1): 8-15.
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