Experimental study on the isothermal adsorption of methane gas in natural gas hydrate argillaceous silt reservoir
Abstract view|0|times PDF download|0|times
Abstract
Gas hydrate occurs in hydrate reservoirs in a solid form. At present, the conventional exploitation method is to decompose solid hydrate and then extract the resulting gaseous gas. Therefore, the occurrence law of gas in a reservoir is of great significance for the study of gas hydrate seepage and productivity. Adsorption, as an important occurrence mode, has been widely concerned in the research on shale reservoirs. However, the adsorption problem in hydrate reservoirs has not received enough attention. In this paper, the existence of adsorption in a hydrate reservoir has been experimentally confirmed for the first time. Based on the argillaceous silt of a natural gas hydrate reservoir in the South China Sea, the pore structure and adsorption characteristics of argillaceous silt were experimentally studied, and the results were compared with those of typical shale reservoirs. The modified Langmuir and Dubinin-Radushevich equations were used to fit the adsorption data, and the suitable adsorption model of argillaceous silt was established and optimized. The results showed that the inhomogeneous slit pores are dominant in argillaceous silt, and they are formed by the accumulation of lamellar particles. Compared with shale, the adsorption capacity of argillaceous silt is weak under the same conditions. However, adsorption is a spontaneous exothermic reaction, and the ambient temperature of argillaceous silt is much lower than that of shale. Therefore, it is possible for argillaceous silt to achieve an adsorption capacity comparable to that of shale. The modified Langmuir model can be used to simulate argillaceous silt adsorption at low pressure, while under medium and high pressures, the modified Dubinin-Radushevich model performs better. The adsorption capacity of argillaceous silt is affected by moisture. When the water content is 20%, the Langmuir adsorption capacity and the Dubinin-Radushevich maximum adsorption capacity decreases by 21.88% and 13.67%, respectively, which is far less than the influence of moisture on shale adsorption, as reported in the literature.
Cited as: Qi, R., Qin, X., Lu, C., Ma, C., Mao, W., Zhang, W. Experimental study on the isothermal adsorption of methane gas in natural gas hydrate argillaceous silt reservoir. Advances in Geo-Energy Research, 2022, 6(2): 143-156. https://doi.org/10.46690/ager.2022.02.06
Keywords
Full Text:
PDFReferences
Barrett, E. P., Joyner, L. G., Halenda, P. P., et al. The deter- mination of pore volume and area distributions in porous substances. I. Computations from nitrogen isotherms. Journal of the American Chemical Society, 1951, 73(1): 373-380.
Busch, A., Gensterblum, Y. CBM and CO2-ECBM related sorption processes in coal: A review. International Journal of Coal Geology, 2011, 87(2): 49-71.
Carty, R. Thermodynamic properties of helium 4 from 2 to 1500 K at pressures to 108 Pa. United States, National Bureau of Standards, 1973.
Chalmers, G. R. L., Bustin, R. M. The organic matter distribu- tion and methane capacity of the Lower Cretaceous strata of Northeastern British Columbia, Canada. International Journal of Coal Geology, 2007, 70(1/3): 223-239.
Chareonsuppanimit, P., Mohammad, S. A., Robinson, R. L., et al. High-pressure adsorption of gases on shales: Measurements and modeling. International Journal of Coal Geology, 2012, 95: 34-46.
Charoensuppanimit, P., Mohammad, S. A., Robinson, R. L., et al. Modeling the temperature dependence of supercritical gas adsorption on activated carbons, coals and shales. International Journal of Coal Geology, 2015, 138: 113- 126.
Clarkson, C., Haghshenas, B. Modeling of supercritical fluid adsorption on organic-rich shales and coal. Paper SPE- 164532-MS Presented at Society of Petroleum Engineers - SPE USA Unconventional Resources Conference, The Woodlands, Texas, 10-12 April, 2013.
Dubinin, M. Porous structure and adsorption properties of active carbons. Chemistry and Physics of Carbon, 1966, 9: 51-119.
Dubinin, M., Astakhov, V. Development of the concepts of volume filling of micropores in the adsorption of gases and vapors by microporous adsorbents. Physical Chem- istry, 1971, 20: 8-12.
Duong, D. D. Adsorption analysis: Equilibria and kinetics. Chemical Engineer Series. 1998, 2: 49-77.
Fletcher, A. J., Thomas, K. M., Rosseinsky, M. J. Flexibility in metal-organic framework materials: Impact on sorp- tion properties. Journal of Solid State Chemistry, 2005, 178(8): 2491-2510.
Gasparik, M., Ghanizadeh, A., Bertier, P., et al. High-pressure methane sorption isotherms of black shales from the Netherlands. Energy & Fuels, 2012, 26(8): 4995-5004.
Gasparik, M., Ghanizadeh, A., Gensterblum, Y., et al. “Multi- temperature” method for high-pressure sorption measurements on moist shales. Review of Scientific Instruments, 2013, 84(8): 085116.
Groen, J. C., Peffer, L. A. A., Pérez-RamíRez, J. Pore size determination in modified micro- and mesoporous ma- terials. Pitfalls and limitations in gas adsorption data analysis. Microporous and Mesoporous Materials, 2003, 60(1): 1-17.
Gurvitsch, L. Physicochemical attractive force. Russian Journal of Physical Chemistry, 1915, 47: 805-827.
Hatch, C. D., Wiese, J. S., Crane, C. C., et al. Water adsorption on clay minerals as a function of relative humidity: Application of BET and freundlich adsorption models. Langmuir, 2012, 28: 1790-1803.
Ji, L., Zhang, T., Milliken, K., et al. Experimental investigation of main controls to methane adsorption in clay-rich rocks. Applied Geochemistry, 2012, 27(12): 2533-2545.
Kapoor, A., Ritter, J. A., Yang, R. T. On the Dubinin- Radushkevich equation for adsorption in microporous solids in the Henry’s law region. Langmuir, 1989, 5(4): 1118-1121.
Li, J., Ye, J., Qin, X., et al. The first offshore natural gas hydrate production test in South China Sea. China Geology, 2018, 1: 5-16.
Li, Y., Li, X., Wang, Y., et al. Effects of composition and pore structure on the reservoir gas capacity of Carboniferous shale from Qaidam Basin, China. Marine and Petroleum Geology, 2015, 62: 44-57.
Liu, B., Gao, Y., Liu, K., et al. Pore structure and adsorption hysteresis of the middle Jurassic Xishanyao shale for- mation in the Southern Junggar Basin, northwest China. Energy Exploration & Exploitation, 2021a, 39: 761-778.
Liu, B., Sun, J., Zhang, Y., et al. Reservoir space and enrichment model of shale oil in the first member of Cretaceous Qingshankou Formation in the Changling sag, southern Songliao Basin, NE China. Petroleum Exploration and Development, 2021b, 48(3): 608-624.
Liu, C., Meng, Q., He, X., et al. Characterization of natural gas hydrate recovered from Pearl River Mouth basin in South China Sea. Marine and Petroleum Geology, 2015, 61(61): 14-21.
Liu, D., Yuan, P., Liu, H., et al. High-pressure adsorption of methane on montmorillonite, kaolinite and illite. Applied Clay Science, 2013, 85: 25-30.
Lu, X., Li, F., Watson, A. T. Adsorption measurements in Devonian shales. Fuel, 1995, 74(4): 599-603.
Luo, X., Wang, S., Wang, Z., et al. Adsorption of methane, carbon dioxide and their binary mixtures on Jurassic shale from the Qaidam Basin in China. International Journal of Coal Geology, 2015, 150-151: 210-223.
Marsh, H. Adsorption methods to study microporosity in coals and carbons—a critique. Carbon, 1987, 25(1): 49-58.
Merkel, A., Fink, R., Littke, R. The role of pre-adsorbed water on methane sorption capacity of Bossier and Haynesville shales. International Journal of Coal Geology, 2015, 147- 148(1): 1-8.
Mohammadi, M. R., Bahmaninia, H., Ansari, S., et al. Evaluation of asphaltene adsorption on minerals of dolomite and sandstone formations in two and three-phase systems. Advances in Geo-Energy Research, 2021, 5(1): 39-52.
Myers, A. L., Monson, P. A. Adsorption in porous materials at high pressure: Theory and experiment. Langmuir, 2002, 18: 10261-10273.
Polanyi, M. Adsorption from the point of view of the Third Law of Thermodynamics. Deutsch Physics, 1914, 16: 1012-1016.
Qi, R. Study on multi-component competitive adsorption mechanism of shale gas. China University of Petroleum, Beijing, 2019. (in Chinese)
Qi, R., Ning, Z., Wang, Q., et al. Measurements and modeling of high-pressure adsorption of CH4 and CO2 on shales. Fuel, 2019, 242(9): 728-743.
Qi, R., Ning, Z.,Wang, Q., et al. Sorption of methane, carbon dioxide, and their mixtures on shales from Sichuan Basin, China. Energy & Fuels, 2018, 32(3): 2926-2940.
Qin, X., Lu, J., Lu, H., et al. Coexistence of natural gas hydrate, free gas and water in the gas hydrate system in the Shenhu Area, South China Sea. China Geology, 2020, 3: 210-220.
Rexer, T. F. T., Benham, M. J., Aplin, A. C. et al., Methane adsorption on shale under simulated geological temperature and pressure conditions. Energy & Fuels, 2013, 27(6): 3099-3109.
Ross, D. J. K., Bustin, R. M. Shale gas potential of the Lower Jurassic Gordondale Member, northeastern British Columbia, Canada. Bulletin of Canadian Petroleum Geology, 2007, 55(1): 51-75.
Ross, D. J. K., Bustin, R. The importance of shale composition and pore structure upon gas storage potential of shale gas reservoirs. Marine and Petroleum Geology, 2009, 26(6): 916-927.
Rouquerol, J., Avnir, D., Fairbridge, C. W., et al. Recommendations for the Characterization of Porous Solids. Pure and Applied Chemistry, 1994, 66(8): 1739-1758.
Ruppel, C. D., Kessler, J. D. The interaction of climate change and methane hydrates. Reviews of Geophysics, 2016, 55(1): 126-168.
Sakurovs, R., Day, S.,Weir, S., et al. Application of a modified Dubinin-Radushkevich equation to adsorption of gases by coals under supercritical conditions. Energy & Fuels, 2007, 21(2): 992-997.
Schettler, P., Parmely, C. Contributions to total storage capacity in Devonian Shales. Paper SPE-23422-MS Presented at the SPE Eastern Regional Meeting, Lexington, Kentucky, 22-25 October, 1991.
Setzmann, U., Wagner, W. A new equation of state and tables of thermodynamic properties for methane covering the range from the melting line to 625 K at pressures up to 100 MPa. Journal of Physical and Chemical Reference Data, 1991, 20(6): 1061-1155.
Shaibu, R., Sambo, C., Guo, B., et al. An assessment of methane gas production from natural gas hydrates: Challenges, technology and market outlook. Advances in Geo-Energy Research, 2021, 5(3): 318-332.
Shen, W., Li, X., Cihan, A., et al. Experimental and numerical simulation of water adsorption and diffusion in shale gas reservoir rocks. Advances in Geo-Energy Research, 2019, 3(2): 165-174.
Sing, K. S. Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity. Pure and Applied Chemistry, 1985, 57(4): 603-619.
Wang, Y., Yu, Q. The effect of moisture on the methane adsorption capacity of shales: A study case in the eastern Qaidam Basin in China. Journal of Hydrology, 2016, 542: 487-505.
Yang, F., Xie, C., Ning, Z., et al. High-pressure methane sorption on dry and moisture-equilibrated shale. Energy & Fuels, 2017a, 31: 482-492.
Yang, F., Xie, C., Xu, S., et al. Supercritical methane sorption on organic-rich shales over a wide temperature range. Energy & Fuels, 2017b, 31: 13427-13438.
Ye, J., Qin, X., Xie, W., et al. The second natural gas hydrate production test in the South China Sea. China Geology, 2020, 3: 197-209.
Zhang, C., Zhou, S., Li, J., et al. Adsorption characteristics of CH4 and CO2 on shale and its application to binary mixture adsorption under high-pressure conditions: A case study of the Longmaxi Formation shale in Jiaoshiba area of Sichuan Basin. Geochimica, 2019, 48(6): 580- 589. (in Chinese)
Zhang, T., Ellis, G. S., Ruppel, S. C., et al. Effect of organic- matter type and thermal maturity on methane adsorption in shale-gas systems. Organic Geochemistry, 2012, 47: 120-131.
Zhou, S., Ning, Y., Wang, H., et al. Investigation of methane adsorption mechanism on Longmaxi shale by combining the micropore filling and monolayer coverage theories. Advances in Geo-Energy Research, 2018, 2(3): 269-281.
Zhou, Y. P., Zhou, L. Fundamentals of high pressure adsorption. Langmuir, 2009, 25: 13461-13466.
Zhu, H., Ju, Y., Huang, C., et al. Microcosmic gas adsorption mechanism on clay-organic nanocomposites in a marine shale. Energy, 2020, 197: 117256.
Zhu, H., Ju, Y., Qi, Y., et al. Impact of tectonism on pore type and pore structure evolution in organic-rich shale: Implications for gas storage and migration pathways in naturally deformed rocks. Fuel, 2018, 228: 272-289.
DOI: https://doi.org/10.46690/ager.2022.02.06
Refbacks
- There are currently no refbacks.
Copyright (c) 2022 The Author(s)
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.