Organic-inorganic interactions of clay minerals and organic matter: Action mechanism and analysis techniques
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Abstract
Elucidating the formation mechanism of organic-rich shale holds significant implications for hydrocarbon exploration, carbon sequestration, and carbon cycling. In recent years, the relationship between organic matter and clay minerals in shale has attracted widespread attention. This study aims to comprehensively overview the interactions between organic matter and clay minerals during deposition and diagenesis. Through sedimentation processes, climate and provenance control the composition of clay minerals in sediments jointly. Meanwhile, clay minerals exhibit selective adsorption of organic matter, thereby influencing the abundance and type of organic matter in sediments. In modern marine depositional environments, the interaction between clay minerals and organic matter significantly impacts the overall activity and burial efficiency of organic carbon. During the diagenesis stage, the presence of organic matter dramatically affects the transformation of smectite into illite. Conversely, the process of smectite illitization also exerts a significant influence on hydrocarbon generation. Furthermore, this study introduces state-of-the-art techniques to investigate the interactions between organic matter and clay minerals.
Document Type: Perspective
Cited as: Xu, S., Zhao, T., Cui, X., Cai, J. Organic-inorganic interactions of clay minerals and organic matter: Action mechanism and analysis techniques. Advances in Geo-Energy Research, 2024, 14(3): 161-164. https://doi.org/10.46690/ager.2024.12.01
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Ahmat, A. M., Boussafir, M., Le Milbeau, C., et al. Organic matter and clay interaction in a meromictic lake: implications for source rock OM preservation (Lac Pavin, Puy de-Dôme, France). Organic Geochemistry, 2017, 109: 47 57.
Blair, N. E., Aller, R. C. The fate of terrestrial organic carbon in the marine environment. Annual Review of Marine Science, 2012, 4: 401-423.
Cai, C., Cai, J., Liu, H., et al. Occurrence of organic matter in argillaceous sediments and rocks and its geological significance: A review. Chemical Geology, 2023, 639: 121737.
Cui, X., Mucci, A., Bianchi, T. S., et al. Global fjords as transitory reservoirs of labile organic carbon modulated by organo-mineral interactions. Science Advances, 2022, 8(46): eadd0610.
Du, J., Cai, J., Chen, Z., et al. A contrastive study of effects of different organic matter on the smectite illitization in hydrothermal experiments. Applied Clay Science, 2019, 168: 249-259.
Fagel, N. Chapter four clay minerals, deep circulation and climate. Developments in Marine Geology, 2007, 1: 139-184.
Feng, X., Simpson, A. J., Simpson, M. J. Chemical and mineralogical controls on humic acid sorption to clay mineral surfaces. Organic Geochemistry, 2005, 36: 1553-1566.
Galán, E. Genesis of clay minerals. Developments in Clay Science, 2006, 1: 1129-1162.
Hedges, J. I., Keil, R. G. Sedimentary organic matter preservation: an assessment and speculative synthesis. Marine Chemistry, 1995, 49: 81-115.
Hemingway, J. D., Rothman, D. H., Grant, K. E., et al. Mineral protection regulates long-term global preservation of natural organic carbon. Nature, 2019, 570: 228-231.
Huang, W., Yang, H., He, S., et al. Thermochemical decomposition reveals distinct variability of sedimentary organic carbon reactivity along the Yangtze River estuary-shelf continuum. Marine Chemistry, 2023, 257: 104326.
Keil, R. G., Mayer, L. M. Mineral matrices and organic matter. Treatise on Geochemistry, 2014, 12: 337-359.
Li, Y., Cai, J., Song, M., et al. Influence of organic matter on smectite illitization: A comparison between red and dark mudstones from the Dongying Depression, China. American Mineralogist, 2016, 101: 134-145.
Smith, R. W., Bianchi, T. S., Allison, M., et al. High rates of organic carbon burial in fjord sediments globally. Nature Geoscience, 2015, 8(6): 450-453.
Sun, X., Fan, D., Hu, L., et al. Oxidation of petrogenic organic carbon in a large river-dominated estuary. Geochimica et Cosmochimica Acta, 2022, 338: 136-153.
Zhao, T., Xu, S., Hao, F. Differential adsorption of clay minerals: Implications for organic matter enrichment. Earth-Science Reviews, 2023, 246: 104598.
DOI: https://doi.org/10.46690/ager.2024.12.01
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