The influence of methyl orange on the CO2-brine wettability of organic-acid-aged calcite samples: Implications for CO2 geo-storage
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Abstract
The underground storage of CO2 in a depleted carbonate formation is a suitable method for limiting its anthropogenic release and minimize global warming. The rock wettability is an essential factor controlling the mechanisms of CO2 trapping and its containment safety in the geo-storage formation. The geo-storage rock contains innate organic acids which alters the wettability of the rock surface from the hydrophilic condition to the hydrophobic state, thus reduce the CO2 storage capacity. In this study, methyl orange which is a toxic dye that is generally released into environment was used as wettability modifier to change the wettability of stearic acid aged calcite (oil wet) to water wet. This study uses the contact angle technique (sessile drop method) to examine the effects of various concentration of methyl orange (10-100 mg/L) on the wettability of the CO2/brine/stearic-acid aged calcite system under geo-storage conditions (i.e., temperatures of 25 and 50 ℃ and pressures of 5-20 MPa). The results indicate that the advancing and receding contact angles (θa and θr) of the organic-acid contaminated rock surface were drastically reduced upon exposure to methyl orange, attaining the minimum values of 62◦ and 58◦ respectively, in the presence of 100 mg/L methyl orange at 20 MPa and 50 ℃. Thus, the present results suggest that rather than discharging methyl orange into the environment, it could be injected into underground reservoirs in order to reduce the level of environmental pollution and at the same time increase the CO2 storage capacity of carbonate formations.
Document Type: Original article
Cited as: Alhammad, F., Ali, M., Yekeen, N., Ali, M., Kamali, M., Iglauer, S., Keshavarz, A. The influence of methyl orange on the CO2-brine wettability of organic-acid-aged calcite samples: Implications for CO2 geo-storage. Advances in Geo-Energy Research, 2024, 12(2): 102-112. https://doi.org/10.46690/ager.2024.05.03
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Abdi, J., Amar, M. N., Hadipoor, M., et al. Modeling of brine/CO2/mineral wettability using gene expression programming (gep): Application to carbon geo-sequestration. Minerals, 2022, 12(6): 760.
Aftab, A., Ali, M., Altaf, M., et al. Influence of stearic acid and alumina nanofluid on CO2 wettability of calcite substrates: Implications for CO2 geological storage in carbonate reservoirs. Journal of Colloid and Interface Science, 2023, 646: 567-575.
Ajayi, T., Gomes, J. S., Bera, A. A review of CO2 storage in geological formations emphasizing modeling, monitoring and capacity estimation approaches. Petroleum Science, 2019, 16(5): 1028-1063.
Al-Anssari, S., Arif, M., Wang, S., et al. CO2 geo-storage capacity enhancement via nanofluid priming. International Journal of Greenhouse Gas Control, 2017a, 63: 20-25.
Al-Anssari, S., Arif, M., Wang, S., et al. Wettability of nano-treated calcite/CO2/brine systems: Implication for enhanced CO2 storage potential. International Journal of Greenhouse Gas Control, 2017b, 66: 97-105.
Al-Anssari, S., Barifcani, A., Wang, S., et al. Wettability alteration of oil-wet carbonate by silica nanofluid. Journal of Colloid and Interface Science, 2016, 461: 435-442.
Al-Anssari, S., Wang, S., Barifcani, A., et al. Effect of temperature and sio2 nanoparticle size on wettability alteration of oil-wet calcite. Fuel, 2017c, 206: 34-42.
Al-Busaidi, I., Al-Maamari, R., Karimi, M., et al. Effect of different polar organic compounds on wettability of calcite surfaces. Journal of Petroleum Science and Engineering, 2019, 180: 569-583.
Al Hameli, F., Belhaj, H., Al Dhuhoori, M. CO2 sequestration overview in geological formations: Trapping mechanisms matrix assessment. Energies, 2022, 15(20): 7805.
Alhammad, F., Ali, M., Ali, M., et al. Effect of methyl orange on wettability of sandstone formations: Implications for enhanced oil recovery. Energy Reports, 2022, 8: 12357-12365.
Alhammad, F., Ali, M., Yekeen, N. P., et al. Effect of methyl orange on the wettability of organic-acid-aged sandstone formations: Implications for CO2 geo-storage. Energy & Fuels, 2023a, 37(22): 17373-17381.
Alhammad, F., Ali, M., Yekeen, N. P., et al. The effect of methylene blue and organic acids on the wettability of sandstone formation: Implications for enhanced oil recovery. Capillarity, 2024, 10(2): 29-37.
Alhammad, F., Sedev, R., Ali, M., et al. Correction to “effect of methyl orange on the hydrogen wettability of sandstone formation for enhancing the potential of underground hydrogen storage”. Energy & Fuels, 2023b, 37(20): 16186-16186.
Ali, M., Al-Anssari, S., Arif, M., et al. Organic acid concentration thresholds for ageing of carbonate minerals: Implications for CO2 trapping/storage. Journal of Colloid and Interface Science, 2019, 534: 88-94.
Ali, M., Awan, F. U. R., Ali, M., et al. Effect of humic acid on CO2-wettability in sandstone formation. Journal of Colloid and Interface Science, 2021, 588: 315-325.
Ali, M., Jha, N. K., Pal, N., et al. Recent advances in carbon dioxide geological storage, experimental procedures, influencing parameters, and future outlook. Earth-Science Reviews, 2022a, 225: 103895.
Ali, M., Yekeen, N., Pal, N., et al. Influence of organic molecules on wetting characteristics of mica/H2/brine systems: Implications for hydrogen structural trapping capacities. Journal of Colloid and Interface Science, 2022b, 608: 1739-1749.
Alnili, F., Al-Yaseri, A., Roshan, H., et al. Carbon dioxide/brine wettability of porous sandstone versus solid quartz: An experimental and theoretical investigation. Journal of Colloid and Interface Science, 2018, 524: 188-194.
Alnoush, W., Sayed, A., Solling, T. I., et al. Impact of calcite surface roughness in wettability assessment: Interferometry and atomic force microscopy analysis. Journal of Petroleum Science and Engineering, 2021, 203: 108679.
Al-Shirawi, M., Karimi, M., Al-Maamari, R. S. Impact of carbonate surface mineralogy on wettability alteration using stearic acid. Journal of Petroleum Science and Engineering, 2021, 203: 108674.
Al-Yaseri, A., Yekeen, N., Ali, M., et al. Effect of organic acids on CO2-rock and water-rock interfacial tension: Implications for CO2 geo-storage. Journal of Petroleum Science and Engineering, 2022, 214: 110480.
Anwar, M., Iftikhar, M., Khush Bakhat, B., et al. Sources of carbon dioxide and environmental issues, in Sustainable Agriculture Reviews 37: Carbon Sequestration Vol. 1 Introduction and Biochemical Methods, edited by A. M. Asiri and E. Lichtfouse, Springer International Publishing, Cham, pp. 13-36, 2019.
Arain, Z. U. A., Aftab, A., Ali, M., et al. Influence of stearic acid and alumina nanofluid on CO2 wettability of calcite substrates: Implications for CO2 geological storage in carbonate reservoirs. Journal of Colloid and Interface Science, 2023, 646: 567-575.
Arif, M., Lebedev, M., Barifcani, A., et al. CO2 storage in carbonates: Wettability of calcite. International Journal of Greenhouse Gas Control, 2017, 62: 113-121.
Baban, A., Keshavarz, A., Amin, R., et al. Residual trapping of CO2 and enhanced oil recovery in oil-wet sandstone core-a three-phase pore-scale analysis using nmr. Fuel, 2023, 332: 12600.
Bikkina, P. K. Contact angle measurements of CO2-water-quartz/calcite systems in the perspective of carbon sequestration. International Journal of Greenhouse Gas Control, 2011, 5(5): 1259-1271.
Broseta, D., Tonnet, N., Shah, V. Are rocks still water-wet in the presence of dense CO2 or H2S? Geofluids, 2012, 12(4): 280-294.
Calandra, S., Cantisani, E., Salvadori, B., et al. Evaluation of atr-ftir spectroscopy for distinguish anthropogenic and geogenic calcite. Journal of Physics: Conference Series, 2022, 2204(1): 012048.
Chakrabarty, D., Mahapatra, S. Aragonite crystals with unconventional morphologies. Journal of Materials Chemistry, 1999, 9: 2953-2957.
Chen, Y., Sari, A., Xie, Q., et al. Insights into the wettability alteration of CO2-assisted EOR in carbonate reservoirs. Journal of Molecular Liquids, 2019, 279: 420-426.
Espinoza, D. N., Santamarina, J. C. Water-CO2-mineral systems: Interfacial tension, contact angle, and diffusion-implications to CO2 geological storage. Water Resources Research, 2010, 46(7): 2009WR008634.
Farokhpoor, R., Bjørkvik, B. J., Lindeberg, E., et al. Wettability behaviour of CO2 at storage conditions. International Journal of Greenhouse Gas Control, 2013a, 12: 18-25.
Farokhpoor, R., Bjørkvik, B. J. A., Lindeberg, E., et al. CO2 wettability behavior during CO2 sequestration in saline aquifer-an experimental study on minerals representing sandstone and carbonate. Energy Procedia, 2013b, 37: 5339-5351.
Hajji, S., Turki, T., Boubakri, A., et al. Study of cadmium adsorption onto calcite using full factorial experiment design. Desalination and Water Treatment, 2017, 83: 222- 233.
Hosseini, M., Ali, M., Fahimpour, J., et al. Assessment of rock-hydrogen and rock-water interfacial tension in shale, evaporite and basaltic rocks. Journal of Natural Gas Science and Engineering, 2022, 106: 104743.
Iglauer, S., Pentland, C., Busch, A. CO2 wettability of seal and reservoir rocks and the implications for carbon geo-sequestration. Water Resources Research, 2015, 51(1): 729-774.
Isac-Garc´ıa, J., Dobado, J. A., Calvo-Flores, F. G., et al. Experimental Organic Chemistry: Laboratory Manual. Amsterdam, Netherland, Elsevier, 2015.
Ivanova, A., Orekhov, A., Strahinja, M., et al. Live imaging of micro and macro wettability variations of carbonate oil reservoirs for enhanced oil recovery and CO2 trapping/storage. Scientific Reports, 2022, 12(1): 1262.
Jaeger, P. T., Alotaibi, M. B., Nasr-El-Din, H. A. Influence of compressed carbon dioxide on the capillarity of the gas-crude oil-reservoir water system. Journal of Chemical & Engineering Data, 2010, 55(11): 5246-5251.
Kanj, M., Sakthivel, S., Giannelis, E. Wettability alteration in carbonate reservoirs by carbon nanofluids. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2020, 598: 124819.
Kelemen, P., Benson, S. M., Pilorge, H., et al. An overview ´ of the status and challenges of CO2 storage in minerals and geological formations. Frontiers in Climate, 2019, 1: 482595.
Keshavarz, A., Akhondzadeh, H., Sayyafzadeh, M., et al. Enhanced gas recovery techniques from coalbed methane reservoirs, in Fundamentals of Enhanced Oil and Gas Recovery from Conventional and Unconventional Reservoirs, edited by Bahadori, A., Elsevier, Amsterdam, pp. 233-268, 2018.
Lai, C. W., Abd Hamid, S. B., Tan, T., et al. Rapid formation of 1d titanate nanotubes using alkaline hydrothermal treatment and its photocatalytic performance. Journal of Nanomaterials, 2015, 2015: 145360.
Le, T. T. B., Striolo, A., Cole, D. R. Supercritical CO2 effects on calcite wettability: A molecular perspective. The Journal of Physical Chemistry C, 2020, 124(34): 18532-18543.
Madsen, L., Lind, I. Adsorption of carboxylic acids on reservoir minerals from organic and aqueous phase. SPE Reservoir Evaluation & Engineering, 1998, 1(1): 47-51.
Memon, S., Feng, R., Ali, M., et al. Supercritical CO2-shale interaction induced natural fracture closure: Implications for sc-CO2 hydraulic fracturing in shales. Fuel, 2022, 313: 122682.
Mills, J., Riazi, M., Sohrabi, M. Wettability of common rock-forming minerals in a CO2-brine system at reservoir conditions. Paper SCA2011-06 Presented at the International Symposium of the Society of Core Analysts, Austin, Texas, 18-21 September, 2011.
Mutailipu, M., Liu, Y., Jiang, L., et al. Measurement and estimation of CO2-brine interfacial tension and rock wettability under CO2 sub-and super-critical conditions. Journal of Colloid and Interface Science, 2019, 534: 605- 617.
Naghizadeh, A., Azin, R., Osfouri, S., et al. Wettability alteration of calcite and dolomite carbonates using silica nanoparticles coated with fluorine groups. Journal of Petroleum Science and Engineering, 2020, 188: 106915.
Nunes, L. J. R. The rising threat of atmospheric CO2: A review on the causes, impacts, and mitigation strategies. Environments, 2023, 10(4): 66.
Ordoñez, L., Vogel, H., Sebag, D., et al. Empowering conventional rock-eval pyrolysis for organic matter characterization of the siderite-rich sediments of lake towuti (indonesia) using end-member analysis. Organic Geochemistry, 2019, 134: 32-44.
Pan, B., Li, Y., Zhang, M., et al. Effect of total organic carbon (toc) content on shale wettability at high pressure and high temperature conditions. Journal of Petroleum Science and Engineering, 2020, 193: 107374.
Rasool, M. H., Ahmad, M., Ayoub, M. Selecting geological formations for CO2 storage: A comparative rating system. Sustainability, 2023, 15(8): 6599.
Roustaei, A., Bagherzadeh, H. Experimental investigation of SiO2 nanoparticles on enhanced oil recovery of carbonate reservoirs. Journal of Petroleum Exploration and Production Technology, 2015, 5(1): 27-33.
Sakthivel, S., Yekeen, N., Theravalappil, R., et al. Influence of carbon nanodots on the carbonate/CO2/brine wettability and CO2-brine interfacial tension: Implications for CO2 geo-storage. Fuel, 2024, 355: 129404.
Santos, V. H. J. M. d., Pontin, D., Ponzi, G. G. D., et al. Application of fourier transform infrared spectroscopy (ftir) coupled with multivariate regression for calcium carbonate (CaCO3) quantification in cement. Construction and Building Materials, 2021, 313: 125413.
Seyyedi, M., Sohrabi, M., Farzaneh, A. Investigation of rock wettability alteration by carbonated water through contact angle measurements. Energy & Fuels, 2015, 29(9): 5544- 5553.
Silvestri, A., Ataman, E., Budi, A., et al. Wetting properties of the CO2-water-calcite system via molecular simulations: Shape and size effects. Langmuir, 2019, 35(50): 16669-16678.
So, R. T., Blair, N. E., Masterson, A. L. Carbonate mineral identification and quantification in sediment matrices using diffuse reflectance infrared fourier transform spectroscopy. Environmental Chemistry Letters, 2020, 18(5): 1725-1730.
Stevar, M. S. P., Böhm, C., Notarki, K. T., et al. Wettability of calcite under carbon storage conditions. International Journal of Greenhouse Gas Control, 2019, 84: 180-189.
Wani, O. B., Lai, C. Y., Quadri, S. M. R., et al. Understanding the wettability of calcite (CaCO3) using higher spatial resolution. Energy & Fuels, 2018, 32(10): 10344-10353.
Yang, D., Gu, Y., Tontiwachwuthikul, P. Wettability determination of the crude oil-reservoir brine-reservoir rock system with dissolution of CO2 at high pressures and elevated temperatures. Energy & Fuels, 2008, 22(4): 2362-2371.
Zhang, D., Song, J. Mechanisms for geological carbon sequestration. Procedia IUTAM, 2014, 10: 319-327.
DOI: https://doi.org/10.46690/ager.2024.05.03
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